Greenhouse Gases Laboratory

Greenhouse Gases Laboratory

The Greenhouse Gases laboratory measures Total Inorganic Carbon (DIC) and Alkalinity (AT), and CH4 in the marine environment.

The determination of DIC and AT is performed with a Versatile INstrument for the Determination (VINDTA) 3C. This is a laboratory alkalinity titration system combined with an extraction unit for coulometric titration, which simultaneously determines the AT and DIC content of a seawater sample. The VINDTA 3C is designed by the company Marianda based in Kiel, Germany (http://www.marianda.com/). The instrument does not require a pressurizing system just a single gas supply (nitrogen or dry and CO2-free air) is necessary. For alkalinity measurements, the system uses a Metrohm Titrino 719S, an ORION-Ross pH electrode and a Metrohm reference electrode. Quality control/quality assurance processes are followed with the use of CRM materials provided by Dr. Andrew Dickson. The instrument’s precision is typically +/- 2 µmol/kg for AT and/or DIC in open ocean water.

The determination of CH4 in seawater and sediment samples is performed on board, after sampling, with an onboard R/V AEGEO Gas Chromatograph with FID for methane determination